Anthropogenic emissions drive global-scale warming yet the temperature increase relative to pre-industrial levels is uncertain. Using 300 years of ocean mixed-layer temperature records preserved in sclerosponge carbonate skeletons, we demonstrate that industrial-era warming began in the mid-1860s, more than 80 years earlier than instrumental sea surface temperature records. The Sr/Ca palaeothermometer was calibrated against ‘modern’ (post-1963) highly correlated (R2 = 0.91) instrumental records of global sea surface temperatures, with the pre-industrial defined by nearly constant (<±0.1 °C) temperatures from 1700 to the early 1860s. Increasing ocean and land-air temperatures overlap until the late twentieth century, when the land began warming at nearly twice the rate of the surface oceans. Hotter land temperatures, together with the earlier onset of industrial-era warming, indicate that global warming was already 1.7 ± 0.1 °C above pre-industrial levels by 2020. Our result is 0.5 °C higher than IPCC estimates, with 2 °C global warming projected by the late 2020s, nearly two decades earlier than expected. Understanding temperature change since the pre-industrial period is essential for climate action. This study uses an ocean proxy to better quantify when anthropogenic warming began and estimates that global temperatures have already increased by 1.7 °C.