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This article contains quite a few technical terms, which I will explain these in the following paragraphs, those that are already familiar with these terms may skip to the next section. A basic understanding of linux and it’s desktop environments is assumed.
Server side decorations (SSD) is the term for when when the application’s titlebar is drawn by the system and client side decorations (CSD) is the term for when the applications draws it’s own titlebar. KDE prefers the former, while GNOME prefers the latter. KDE and most other desktop environments supports both, while GNOME only supports CSD.
There are some very convincing Windows themes. Gnome, too. There are a couple to make it look exactly like the IRIX theme, or CDE.
Personally, I think the default layout is plenty simple. You press the applications icon, you press on the thing you want, that thing opens.
If you can take twenty seconds to set it up for them, run everything they’ll ever want to run, right-click on it in the task bar, click Pin to Task Manager.
Then all they’ll ever need to do is poke the one they want to run and it runs.
KDE also has a Mobile DE called Plasma Mobile. Looks like it can be installed on desktops and laptops too.